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Synthesis and structure of the chiral palladium–fullerene C60 and C70 complexes with enantiomeric ligand 2,2′,5,5′-tetramethyl-4,4′-bis(diphenylphosphino)-3,3′-bithiophene [(−)tetraMe-BITIOP]

✍ Scribed by Vasily V. Bashilov; Feodor M. Dolgushin; Pavel V. Petrovskii; Viatcheslav I. Sokolov; Mara Sada; Tiziana Benincori; Gianni Zotti


Book ID
108188091
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
361 KB
Volume
690
Category
Article
ISSN
0022-328X

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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th