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Synthesis and Structure of Ta4S9Br8. An Emergent Family of Early Transition Metal Chalcogenide Clusters.

โœ Scribed by Maxim N. Sokolov; Artem L. Gushchin; Pavel A. Abramov; Alexandr V. Virovets; Eugenia V. Peresypkina; Svetlana G. Kozlova; Boris A. Kolesov; Cristian Vicent; Vladimir P. Fedin


Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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Synthesis and Crystal Structures of Cs5N
โœ Maxim Sokolov; Hideo Imoto; Taro Saito; Vladimir Fedorov ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 197 KB ๐Ÿ‘ 2 views

Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4ยฑ (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4ยฑ in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st