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Synthesis and Structure of [Ni(PtBu6)] and [Ni5(PtBu)6(CO)5] and Calculations on the Electronic Structure of [Ni(PtBu)6] and (PR)6, R = tBu,Me

✍ Scribed by Prof. Dr. Reinhart Ahlrichs; Prof. Dr. Dieter Fenske; Dipl.-Chem. Hannes Oesen; Dipl.-Chem. Uwe Schneider

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
617 KB
Volume
31
Category
Article
ISSN
0044-8249

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✦ Synopsis

Fig. 4. Molecular structure of6 (C atoms omitted for clarity). Ni: blue, Se: red, P: green. Important distances (f 0.2 pm) and angles (k 0.1 "): In the cuboctahedron: Ni-Ni 260.6-272.4, Nil I-Ni 257.6-280.0; in den Ni,-Kuben: Nil-Ni2 263.8, Ni2-Ni3 265.7, Ni3-Ni4 265.1, Nil-Ni7 262.1, Ni2-Ni8 259.3, Ni3-Ni5 261.4. Ni4-Ni6 262.3, (pc,-Se)-Ni 231.0-241.9, Ni-P 219.4-225.8; Ni2-Nil-Ni7 91.1. Nil-Ni4-Ni390.3.Ni6-Nill-Ni76l,l,Ni8'-Nill-Ni562.0, Ni7

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