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ChemInform Abstract: Crystal Structure and Magnetic Properties of Ce7Ni5.+-.xGe3 .+-.xIn6 and Pr7Ni5.+-.xGe3 .+-.xIn6.

✍ Scribed by Nataliya Chumalo; Galyna P. Nychyporuk; Volodymyr V. Pavlyuk; Rainer Poettgen; Dariusz Kaczorowski; Vasyl' I. Zaremba

Publisher
John Wiley and Sons
Year
2011
Weight
21 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Crystal Structure and Magnetic Properties of Ce 7 Ni 5Β±x Ge 3Β±x In 6 and Pr7Ni5Β±xGe3Β±xIn6. -Ce7Ni4.73Ge3.27In6 and Pr7Ni4.96Ge3.04In6 are prepared by arc-melting of the elements and characterized by single crystal XRD and magnetic measurements. The compounds crystallize in the space group P6/m with Z = 1. The new structure type can be derived from the AlB2-type structure by substitution of the Al and B atoms by CeM 12 (M: Ge/Ni) hexagonal prisms an tricapped trigonal prismatic NiIn 6 Ce 3 polyhedra. Polycrystallin Ce7Ni5Ge3In6 shows Curie-Weiss like paramagnetic behavior down t 1.

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