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Synthesis and Structure of [Ni{Ga−C(SiMe 3 ) 3 } 4 ] and Quantum-Chemical Verification of Strong π Back-Bonding in the Model Compounds [Ni(EMe) 4 ] (E = B, Al, Ga, In, Tl)

✍ Scribed by Uhl, Werner; Benter, Maike; Melle, Sandra; Saak, Wolfgang; Frenking, Gernot; Uddin, Jamal


Book ID
124094762
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
67 KB
Volume
18
Category
Article
ISSN
0276-7333

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Why are the Homoleptic Diyl Complexes M(
✍ Markus Doerr; Gernot Frenking 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 345 KB 👁 2 views

The equilibrium geometries and first bond dissociation energies of the homoleptic complexes M(EMe) 4 and M(CO) 4 with M ϭ Ni, Pd, Pt and E ϭ B, Al, Ga, In, Tl have been calculated at the gradient corrected DFT level using the BP86 functionals. The electronic structure of the metal-ligand bonds has b