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Synthesis and Structure of Na2[(HO3PCH2)3NH]1.5H2O: The First Alkaline Triphosphonate

✍ Scribed by H. Silvia Martı́nez-Tapia; Aurelio Cabeza; Sebastián Bruque; Pilar Pertierra; Santiago Garcı́a-Granda; Miguel A.G. Aranda


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
301 KB
Volume
151
Category
Article
ISSN
0022-4596

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✦ Synopsis


Sodium nitrilotris(methylenephosphonate), Na 2 [(HO 3 PCH 2 ) 3 NH]1.5H 2 O, has been synthesized as single crystals and as bulk polycrystalline single phase. This compound is triclinic, space


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A new compound containing polyoxovanadoborate anion was synthesized and characterized by single-crystal X-ray diffraction analysis. A water molecule at the center of the anion was precisely determined. The crystals of the new compound belong to the monoclinic system, space group P2 1 /n with a=1.350