Synthesis and Structure of [Li(thf)4]2(Ph2P)10Cd4] Containing a Dianion with a Cd4P10 Adamantanoid Core
β Scribed by Dr. Michael A. Beswick; Dr. Paul R. Raithby; Christopher A. Russell; Dr. Alexander Steiner; Kerry L. Verhorevoort; Gregory N. Ward; Dr. Dominic S. Wright
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 399 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0044-8249
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The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 Β°C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 Β°C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst
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