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Synthesis and Structure of Di-μ-oxo-bistripyrazolylborato Dioxo Vanadium (V) Complex with Lattice of Diacetonitrile

✍ Scribed by Yong Heng Xing; Katsuyuki Aoki; Feng Ying Bai; Yuan Hong Zhang; Bao Li Zhang


Publisher
Springer
Year
2008
Tongue
English
Weight
216 KB
Volume
38
Category
Article
ISSN
1572-8854

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n Bu 4 N][Re(O)Cl 4 ] or [Re(O)Cl 2 (OEt)(PPh 3 ) 2 ] react with PCOOH (2-(diphenylphosphanyl)benzoic acid) in different stoichiometries leading to the mono-substituted complexes [ n Bu 4 N][Re(O)Cl 3 (PCOO)] (2) and [Re(O)Cl 2 (PCOO)(PPh 3 )] (5), respectively. In CH 2 Cl 2 -MeOH, 2 rearranges part