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Synthesis and structure of di-μ-hydroxo-bis[bis(dimethyl sulfoxide)platinum(II)] perchlorate

✍ Scribed by Rochon, F. D. ;Kong, P. C. ;Melanson, R.

Book ID
114503206
Publisher
International Union of Crystallography
Year
1985
Tongue
English
Weight
418 KB
Volume
41
Category
Article
ISSN
0108-2701

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The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c