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Synthesis and structure of Cu1+4Mo6+5O17

✍ Scribed by E.M. McCarron III; J.C. Calabrese


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
737 KB
Volume
65
Category
Article
ISSN
0022-4596

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NH 4 ) 2 [Mo 6 Cl 14 ] Β΄H2 O (1) was prepared from reactions of MoCl 2 in ethanol with aqueous NH 4 Cl solution. It crystallizes in the monoclinic space group I2/a (no. 15), Z = 4 with a = 912.3(1), b = 1491.2(2), c = 1724.8(2) pm, b = 92.25(1)Β°; R1 = 0.023 (based on F values) and wR2 = 0.059 (based