Synthesis and Crystal Structure of K6Mo10O33.
β Scribed by Nachiappan Arumugam; Eva-Maria Peters; Martin Jansen
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 12 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
(Mo, \(\mathrm{Nb})_{13} \mathrm{O}_{33}\) crystallizes in the triclinic system, space group \(P 1\) (No. 2). The unit cell dimensions are \(a=3.8194(4) \AA, b=\) \(11.2898(7) \AA, c=14.9764(9) \AA, \alpha=94.039(5)^{\circ}, \beta=97.326(6)^{\circ}\), \(\gamma=99.748(7)^{\circ}, V=628.47(9) \AA^{3}\
Ethylenediamine trimolybdate, (C 2 H 10 N 2 ) [Mo 3 O 10 ], has been hydrothermally synthesized (180Β°C, 24 h, autogeneous pressure). It crystallizes in the monoclinic system (space group P2 1 /n) with a β«Ψβ¬ 8.0865(2) A s , b β«Ψβ¬ 14.4902(2) A s , c β«Ψβ¬ 8.9306(2) A s , β«Ψβ¬ 98.170(1)Β°, and Z β«Ψβ¬ 4. Its
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