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Synthesis and structure of (carbonyl){μ-η5: η1-[2-(N,N-dimethylamino)ethyl]cyclopentadienyl}(dichlorogallio)nickel(II)

✍ Scribed by Holger Hoffmann; Roland A. Fischer; Björn Antelmann; Gottfried Huttner


Book ID
108354780
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
96 KB
Volume
584
Category
Article
ISSN
0022-328X

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✍ Priv.-Doz. Dr. Fritz R. Kreissl; Dipl.-Chem. Gabriele Reber; Dr. Gerhard Müller 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

Reaction of 5 with transition-metal halides affords sandwich and triple-decker complexes. For example, reaction with [((C,Me,)RuCl,},] furnishes the yellow 18e complex 7,14.81 while reaction with [((1,5-cod)RhCI),] leads to formation of the dark-red, 30e triple-decker complex 8 .[4.91