Synthesis and Structure of Triphenylscan
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Markus A. Putzer; Glenn P. Bartholomew
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Article
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1999
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John Wiley and Sons
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German
β 62 KB
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Metathesis reaction of ScCl 3 (THF) 3 with 3 equiv. of phenyllithium in THF/Et 2 O solution affords ScPh 3 (THF) 2 (1) in good yield. The crystallographically determined molecular structure of 1 reveals a trigonal-bipyramidal coordination sphere with the THF molecules in the axial positions and ScΒ±C