Synthesis and Structure of Bis(tri-tert-butylphenyl)iminohalogenphosphoranes XP(NtBu3C6H2)2
β Scribed by Dr. Alexander Ruban; Dr. Martin Nieger; Prof. Dr. Edgar Niecke
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 297 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The iminophosphane (Me 3 Si) 3 CΟͺP=NΟͺMes\* (1) reacts with Chlorine/bromine exchange in 3 with bromotrimethylsilane affords the bromo analogue 4. The structures of 2, 3 and 4 iodine to form the imino(methylene)phosphorane IΟͺP-(=NΟͺMes\*)=C(SiMe 3 ) 2 (2). Upon subsequent treatment with were confirmed
A photochemical precursor to a pendant conjugated polyradical has been synthesized, poly [3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butylphenyl)oxalato]phenylacetylene], 3. Irradiation of 3 at 77 K in the solid state at Γ΅ 300 nm yielded poly(3-5-ditert-butyl-2-oxyphenyl acetylene), 2, with 30-40% of the