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Synthesis and structure of bis(2,4,6-tri-tert-butylphenyl)diphosphene: isolation of a true phosphobenzene

✍ Scribed by Yoshifuji, M.; Shima, I.; Inamoto, N.; Hirotsu, K.; Higuchi, T.


Book ID
120234558
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
413 KB
Volume
103
Category
Article
ISSN
0002-7863

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Reaction of (E)-bis(2,4,6-tri-tert-butyl
✍ Matthias Freytag; Peter G. Jones; Reinhard Schmutzler; Masaaki Yoshifuji πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 221 KB

## Abstract The reactions of (__E__)‐bis(2,4,6‐tri‐tert‐butylphenyl)diphosphene with tetrachloro‐o‐benzoquinone gave two products of interest, a spirophosphorane and a 1,3,2‐dioxaphospholane, indicating cleavage of the P=P bond. The structures were determined by X‐ray crystallographic analyses. Β© 2