This paper presents two methods for the synthesis of the first reaction of [(Me 3 Si) 2 NB(C 5 H 5 ) 2 ], prepared in situ, with Ti(NMe 2 ) 4 and converted into the chloro derivatives [1]boratitanocenophanes. The novel biscyclopentadienylborane [(Me 3 Si) 2 NB(C 5 H 5 ) 2 ], the dilithio salt Li 2 [
โฆ LIBER โฆ
Synthesis and structure of anhydroindanone-1 disulfide
โ Scribed by Konstantin A. Rufanov; Alexander S. Stepanov; Dmitry A. Lemenovskii; Andrei V. Churakov
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 149 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
โฆ Synopsis
An unexpectedly high yield of anhydroindanone-1 disulfide (1) was obtained by reaction of Lawesson's reagent with indanone-1. The molecular structure of 1 was established by X-ray diffraction. A possible mechanism of the reaction is discussed.
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