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Synthesis and Structure of a 1H-Diphosphirene

✍ Scribed by Prof. Dr. Edgar Niecke; Dipl.-Chem. Rainer Streubel; Dr. Martin Nieger; Dr. Dietmar Stalke


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
252 KB
Volume
28
Category
Article
ISSN
0044-8249

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An unexpectedly high yield of anhydroindanone-1 disulfide (1) was obtained by reaction of Lawesson's reagent with indanone-1. The molecular structure of 1 was established by X-ray diffraction. A possible mechanism of the reaction is discussed.

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extensively flatten the molecular skeleton around the nitrogen atoms and that the SiNSi angle (presumably near 120") will therefore change less than the CNC angle. 2) The 14N coupling constant of the tetrakis(trimethylsily1)hydrazine radical cation is at least 3 G smaller than that of analogous tet