Synthesis and structure of and DFT-studies on 1,3,5-[P(O)(i-PrO)2]3C6H3 and its CHCl3 adduct: analysis of the Cl3C–H⋯OP hydrogen bond
✍ Scribed by Markus Henn; Klaus Jurkschat; Dirk Mansfeld; Michael Mehring; Markus Schürmann
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 228 KB
- Volume
- 697
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The prolonged photo-Arbuzov reaction (3 weeks, Hg lamp) of 1,3,5-trichloro-benzene with a large excess of trimethyl phosphite (as a solvent) at 508 gives moderate yields of dimethyl (3,5-dichlorophenyl)phosphonate (1; 14.5%), tetramethyl (5-chloro-1,3-phenylene)bis[phosphonate] (2; 35.4%), and hexam
The iminophosphane (Me 3 Si) 3 CϪP=NϪMes\* (1) reacts with Chlorine/bromine exchange in 3 with bromotrimethylsilane affords the bromo analogue 4. The structures of 2, 3 and 4 iodine to form the imino(methylene)phosphorane IϪP-(=NϪMes\*)=C(SiMe 3 ) 2 (2). Upon subsequent treatment with were confirmed