The synthesis, properties and X-ray crystal structure of ## [Ni(Me3112]N3)(O2N)(H20)](ClO4).2H20, in which Me3[12]N 3 is 2,4,4-trimethyl-l,J,9-triazacyclododec-1ene, are described. The Ni atom is octahedrally coordinated to three N atoms of the macrocycle, two O atoms of the nitrito group and one
β¦ LIBER β¦
Synthesis and structure of a terephthalato-bridged nickel complex [Ni(tpt)(imi)3(H2O)]n
β Scribed by Quanzheng Zhang; Canzhong Lu
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 97 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1572-8854
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## Abstract [Bu~4~N][Ni(mdt)~2~] (H~2~mdt = 2__H__β1,3βdithioleβ4,5βdithiol) has been prepared in a threeβstep synthesis from [Bu~4~N]~2~[Zn(dmit)~2~] (H~2~dmit = 2βthioneβ1,3βdithioleβ4,5βdithiol). The crystal structure is reported which shows that the Ni(mdt)~2~ anion is distorted significantly f