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Synthesis and Structure of a Novel Type of Polyoxomolybdate Lanthanide Complex: [(Ln(H2O)6)2 (TeMo6O24)] (Ln: Ho, Yb).

✍ Scribed by Daniel Drewes; Bernt Krebs


Publisher
John Wiley and Sons
Year
2006
Weight
15 KB
Volume
37
Category
Article
ISSN
0931-7597

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 Β°C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4β€’H2O. The isostructural compounds crystallize in the m