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Open-Framework Polar Compounds: Synthesis and Characterization of Rare-Earth Polyoxometalates (C6NO2H5)2 [Ln(H2O)5 (CrMo6H6O24)]×0.5H2O (Ln: Ce and La).

✍ Scribed by Haiyan An; Dongrong Xiao; Enbo Wang; Yangguang Li; Xinlong Wang; Lin Xu


Publisher
John Wiley and Sons
Year
2005
Weight
15 KB
Volume
36
Category
Article
ISSN
0931-7597

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Open-Framework Polar Compounds: Synthesi
✍ Haiyan An; Dongrong Xiao; Enbo Wang; Yangguang Li; Xinlong Wang; Lin Xu 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB

## Abstract Two unprecedented open‐framework polar compounds (C~6~NO~2~H~5~)~2~[Ln(H~2~O)~5~(CrMo~6~H~6~O~24~)]·0.5H~2~O [Ln = Ce (1), La (2); C~6~NO~2~H~5~ = pyridine‐3‐carboxylic acid], constructed from Anderson‐type polyoxo anions and rare‐earth cations, have been synthesized for the first time