The First Vanadium Gallophosphates: Hydr
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Robert P. Hammond; Jon A. Zubieta
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Article
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1999
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Elsevier Science
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English
⚖ 282 KB
The 5rst examples of vanadium gallophosphates, Rb[(VO)(H2O)Ga(PO4)2] and Cs[(VO)(H2O)Ga(PO4)2] have been synthesized using hydrothermal methods, from XVO3 (X ؍ Rb, Cs), Ga2O3, H3PO4, H2PO3F, and an organic species. The phases are isostructural and have a three-dimensional anionic vanadium gallopho