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A Hydrothermal Investigation of the 1 / 2 V 2 O 5 −H 2 C 2 O 4 /H 3 PO 4 /NH 4 OH System: Synthesis and Structures of (NH 4 )VOPO 4 ·1.5H 2 O, (NH 4 ) 0.5 VOPO 4 ·1.5H 2 O, (NH 4 ) 2 [VO(H 2 O) 3 ] 2 [VO(H 2 O)][VO(PO 4 ) 2 ] 2 ·3H 2 O, and (NH 4 ) 2 [VO(HPO 4 )] 2 (C 2 O 4 )·5H 2 O

✍ Scribed by Do, Junghwan; Bontchev, Ranko P.; Jacobson, Allan J.


Book ID
125813220
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
312 KB
Volume
39
Category
Article
ISSN
0020-1669

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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2.5 , monoclinic C2/m, a ‫؍‬ 18.425(4) A ˚, c ‫؍‬ 8.954(2) A ˚, ␤ ‫؍‬ 93.69(2) 0 , V ‫؍‬ 1221.1(4) A ˚3, Z ‫؍‬ 4, D calc ‫؍‬ 2.423 g cm ؊3 ; 2 ؒ H 2 O, H 4 F 2 K 2 O 13 P 2 V 3 , triclinic P1, a ‫؍‬ 7.298(1) A ˚, b ‫؍‬ 8.929(2) A ˚, c ‫؍‬ 10.090(2) A ˚, ␣ ‫؍‬ 104.50(2) 0 , ␤ ‫؍‬ 100.39(2) 0 , ␦ ‫؍‬

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✍ Michael Schindler; Werner Joswig; Werner H. Baur 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 333 KB

4؉ , and As 5؉ , but none of them crystallize in space group Pn2n. In the K/V/P/N(C 2 H 5 ) 3 / H 2 O system, three different K phases were found: K 0.5 VOPO 4 • 1.5H 2 O, KVOPO 4 , and K-FVP-1 (Frankfurt vanadium phosphate, one, or for short, FVP-1). The microporous K-FVP-1 compound was synthesize

Hydrothermal Synthesis and Characterizat
✍ Junghwan Do; Ranko P. Bontchev; Allan J. Jacobson 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 488 KB

Two new phases, (C 4 H 12 N 2 )(H 3 O)[(VOPO 4 ) 4 (H 2 O)H 2 PO 4 ] ' 3H 2 O (1) and (C 4 H 12 N 2 )[(VO)(VO 2 ) 2 (H 2 O)(PO 4 ) 2 ] (2) have been synthesized hydrothermally and characterized by single crystal X-ray di4raction, thermogravimetric analysis, and magnetic susceptibility. Compound 1 ha