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Synthesis and structure of a novel aluminium phosphate anion: (Al3P4O16)3?

โœ Scribed by Jones, Richard H.; Thomas, John M.; Xu, Ruren; Huo, Qisheng; Cheetham, Anthony K.; Powell, Anthony V.


Book ID
127173286
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
320 KB
Volume
18
Category
Article
ISSN
0022-4936

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A Novel Framework Antimony (III) Phospha
โœ Brian A. Adair; Graciela Dฤฑ́az de Delgado; J. Miguel Delgado; Anthony ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 285 KB

The antimony (III) phosphate, NaSb 3 O 2 (PO 4 ) 2 , is a framework structure built from Sb III and P V centers; orthorhombic, space group Pca2 1 (No. 29), a โ€ซุโ€ฌ 13.944( 3), b โ€ซุโ€ฌ 6.6822( 13), c โ€ซุโ€ฌ 20.886(4) A > , V โ€ซุโ€ฌ 1946.1(7) A > 3 , Z โ€ซุโ€ฌ 8. Stereochemically active lone pairs of electrons asso