The oxysulfide anion [NbS3O]3−: Synthesis and crystal structure of Ba6(NbS4)(NbS3O)3
✍ Scribed by L.E. Rendon-Diazmiron; C.F. Campana; H. Steinfink
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 410 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-4596
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Single crystals of \(\mathrm{Ba}_{5} \mathrm{Nb}_{3} \mathrm{O}_{3} \mathrm{~F}_{18}\left(\mathrm{HF}_{2}\right)\) are grown by hydrothermal synthesis. The crystal structure is established from single-crystal X-ray diffraction data: S. G. \(P 6_{3} / m, Z=2, a=11.935(1) \AA\), and \(c=7.852(1) \AA\l
The title compound has been synthesized and its structure refined by using powder diffraction data. The structure is orthorhombic, space group Immm, with cell constants \(a=7.1156(9), b=10.2863\) (18), \(c=6.5756\) (9) \(\AA\), and \(Z=4\). Two types of \(\mathrm{Nb}\) atoms are present in the struc
Single crystals of \(\mathrm{Ba}_{3} \mathrm{Nb}_{2} \mathrm{O}_{2} \mathrm{~F}_{12} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) were grown by hydrothermal synthesis in \(\mathrm{HF}\) aqueous solutions. The structure is established from single crystal X-ray diffraction data: S.G. \(C m c 2_{1}, Z=4, a=22.6