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Synthesis and Structure of a Discrete Hexanuclear Uranium–Phosphate Complex

✍ Scribed by Ladd M. Mokry; Dr. Norman S. Dean; Prof. Carl J. Carrano


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
319 KB
Volume
35
Category
Article
ISSN
0044-8249

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Introducing cobalt into the Zn-P-O-amine system and using oxalates as starting materials, an amine-containing openframework zinc cobalt phosphate, [C 2 N 2 H 10 ][Co 4.2 Zn 1.8 (PO 4 ) 4 (HPO 4 )] . H 2 O (1), has been hydrothermally synthesized. It crystallizes in monoclinic space group C2=c (No. 1