Synthesis and Structure of a Cyclic Complex of Digold Sulfide Au2S and of Related Compounds
β Scribed by Hofreiter, Stefan ;Paul, Martin ;Schmidbaur, Hubert
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1995
- Tongue
- English
- Weight
- 475 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0009-2940
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A new quaternary rare-earth sulfide has been isolated and identified. Crystals of La 6 MgGe 2 S 14 , as well as of the previously identified La 6 MgSi 2 S 14 have been grown from a mixed binaryhalide eutectic flux. They both crystallize in the hexagonal space group C 6 6 -P6 3 , with Z" "1. The crys
## Abstract Treatment of 2,6βbis(diphenylphosphino)β4,4βbis(4βnβbutylphenyl)dithienosilole with chloro(dimethylsulfide)gold(I) in acetone gave the corresponding digold complex as pale green solids. The complex was highly emissive and showed blue photoluminescence with the quantum efficiencies of Ξ¦