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Synthesis and Structure Determination of Tellurium Tetracyanide Solvates: Pseudopolymorphism of Te(CN)4 and TeF4

✍ Scribed by Dieter Lentz; Małgorzata Szwak


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
178 KB
Volume
44
Category
Article
ISSN
0044-8249

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✍ Josef Novosad; Sergey V. Lindeman; Jaromir Marek; J. Derek Woollins; Steinar Hus 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB

Reaction of K[(SePPh 2 ) 2 N] with [Te(tu) 4 ]Cl 2 (tu ‫ס‬ thiourea) in methanol gave [Te{(SePPh 2 ) 2 N} 2 ], (1), while reaction of K[(SPPh 2 ) 2 N] with 4-MeOPhTeCl 3 in methanol gave [4-MeOPhTe-{(SPPh 2 ) 2 N}] 2 , ( 2). The crystals of 1 are triclinic and contain centrosymmetric molecules. The