a white crystalline product, which, after a single recrystallization, affords fine needles of the [12]crown-4 complex ## 5 . @ ] Addition of 2,2'-bipyridine (bpy) to the solution of the recrystallized complex 5 gives [Fe(bpy),] (PF6)2 and two molar equivalents of [12]crown-4. The single-crystal X-
✦ LIBER ✦
Synthesis and Structure Determination of Bicyclic [Li(tmeda)]2[S6]
✍ Scribed by Dr. Kazuyuki Tatsumi; Yoshihisa Inoue; Dr. Akira Nakamura; Prof. Dr. Roger E. Cramer; Prof. Dr. William VanDoorne; Prof. Dr. John W. Gilje
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 400 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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A new compound, Li 3 AlB 2 O 6 , has been synthesized by solid state reaction and its structure has been solved and re5ned from single-crystal and power X-ray di4raction data. This compound crystallizes in a triclinic unit cell (space group P1 ) with lattice parameters a ؍ 4.876(8) A s , b ؍ 6.1