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Synthesis and structure assignments of cis- and trans-2-(diethylaminomethyl)cyclohexanols

✍ Scribed by Mohindar S. Puar; Allen I. Cohen; John Krapcho

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
343 KB
Volume
7
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The synthesis of cis‐ and trans‐2‐(diethylaminomethyl)‐cyclohexanols and their structural assignments by NMR using the shift reagent Eu(dpm)~3~ are described. The correlation of the induced shifts with the equation Δν = K(3 cos^2^θ – 1)r^−3^, assuming an EuO distance of 2·4 Å and θ less than 30°, suggests that the interactions are pseudocontact. The values of K are 452 and 420 for the two cyclohexanols, respectively.

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