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Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines

✍ Scribed by Dionisia Sanz; María Alejandra Ponce; Rosa María Claramunt; Cristina Fernández-Castaño; Concepción Foces-Foces; José Elguero

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
195 KB
Volume
12
Category
Article
ISSN
0894-3230

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✦ Synopsis

The synthesis and spectroscopic properties ( 1 H, C and 15 N NMR, in solution and in the solid state) of six new 1-adamantylmethylene azines are reported. The crystal and molecular structures of 1-adamantylcarbaldehyde azine and 1-adamantyl methyl ketone azine, which exist in the solid state in the E,E-configuration, were determined by x-ray analysis. The geometric characteristics of the azine central bridge and the preferred configuration with regard to it (E,E, E,Z or Z,Z) were investigated by means of the crystallographic data retrieved from the Cambridge Structural Database and ab initio quantum chemical calculations.

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