The reductive coupling of chlorotris(diorganylamino)silanes 1 with chlorotrimethylsilane by the action of lithium in THF provides for steric reasons, an easy access to unsymmetrical aminosubstituted disilanes (R 2 N) 3 Si-SiMe 3 3. Similarly, crosscoupling to give pentakis(diethylamino)disilane 4 is
โฆ LIBER โฆ
ChemInform Abstract: Aminosubstituted Disilanes: Synthesis by Unsymmetrical and Symmetrical Reductive Coupling.
โ Scribed by J. HEINICKE; S. MANTEY
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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