## Abstract Reactions of pyrazine (Pyz = C~4~H~4~N~2~) with [MoOCl~4~(H~2~O)]^–^ or [MoOBr~4~]^–^ afforded a series of complexes, dinuclear [(MoOX~4~)~2~(Pyz)]^2–^ (X = Cl, Br), [{MoOCl~3~(Pyz)}~2~O]^2–^ and tetranuclear [(Mo~2~O~4~Cl~4~)~2~(Pyz)~2~]^4–^ anions, with N‐donor ligands engaged either
✦ LIBER ✦
Synthesis and structural studies of dimeric molybdenum(V) complexes with acetylacetonate
✍ Scribed by Jarosław Sobczak; Józef J. Ziółkowski
- Publisher
- Springer
- Year
- 1983
- Tongue
- English
- Weight
- 193 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0340-4285
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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## Abstract Reaction of WX~6~ (X = Cl or Br) with O(SiMe~3~)~2~ in CH~2~Cl~2~, followed by addition of MeCN and a further equivalent of O(SiMe~3~)~2~ in CH~2~Cl~2~ gives [WO~2~X~2~(MeCN)~2~] in situ, which subsequently react with the dithioethers MeS(CH~2~)~2~SMe, __i__PrS(CH~2~)~2~S__i__Pr or 1,4‐