Acyl complexes of molybdenum: structural and reactivity studies
✍ Scribed by Leopoldo Contreras; Antonio Pizzano; Luis Sánchez; Ernesto Carmona
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 650 KB
- Volume
- 500
- Category
- Article
- ISSN
- 0022-328X
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Reactions of the complex [MoCl(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (phen=1,10-phenanthroline) with potassium arylamides were used to synthesize the amido complexes [Mo(N(R)Ar)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (R=H, Ar=Ph, 2 a; R=H, Ar=p-tolyl, 2 b; R=Me, Ar=Ph; 2 c). For 2 b the Mo-N(amido) b
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