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Synthesis and structural characterization of some molybdenum carbonyl nitrosyl complexes of diethyldithiocarbamate

โœ Scribed by Kom-Bei Shiu; Sheng-Ting Lin; Shie-Ming Peng; Ming-Chu Cheng

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
933 KB
Volume
229
Category
Article
ISSN
0020-1693

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## Abstract Reactions of pyrazine (Pyz = C~4~H~4~N~2~) with [MoOCl~4~(H~2~O)]^โ€“^ or [MoOBr~4~]^โ€“^ afforded a series of complexes, dinuclear [(MoOX~4~)~2~(Pyz)]^2โ€“^ (X = Cl, Br), [{MoOCl~3~(Pyz)}~2~O]^2โ€“^ and tetranuclear [(Mo~2~O~4~Cl~4~)~2~(Pyz)~2~]^4โ€“^ anions, with Nโ€donor ligands engaged either