Synthesis, structure and properties of molybdenum(0) bialkyne complexes
β Scribed by J.S. Lain; C.H. Cheng; C.Y. Cheng; S.L. Wang
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 327 KB
- Volume
- 390
- Category
- Article
- ISSN
- 0022-328X
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π SIMILAR VOLUMES
The complex chemical behaviour of 2-phosphaindolizines 1 strong upfield signal (Ξ΄ 31 P = 6.1) was observed with a coordination shift of βΞ΄ = -161.7, which is typical for Ο-(1,3-azaphospholo[1,5-a]pyridines) towards metal carbonyl compounds was studied. (Ξ· 1 -2-Phosphaindolizine)M(CO) 5 coordination.
Bis-Dinitrogen and Diethylene Complexes of Molybdenum(O)\*\*
Reactions of the complex [MoCl(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (phen=1,10-phenanthroline) with potassium arylamides were used to synthesize the amido complexes [Mo(N(R)Ar)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (R=H, Ar=Ph, 2 a; R=H, Ar=p-tolyl, 2 b; R=Me, Ar=Ph; 2 c). For 2 b the Mo-N(amido) b