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Synthesis and structural characterization of novel tetranuclear organotitanoxane derivatives

✍ Scribed by Ventura, María; Ramírez de Arellano, Carmen; Mosquera, Marta E. G.; Jiménez, Gerardo; Cuenca, Tomás

Book ID
120314766
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
335 KB
Volume
40
Category
Article
ISSN
1477-9226

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## Abstract Reactions of pyrazine (Pyz = C~4~H~4~N~2~) with [MoOCl~4~(H~2~O)]^–^ or [MoOBr~4~]^–^ afforded a series of complexes, dinuclear [(MoOX~4~)~2~(Pyz)]^2–^ (X = Cl, Br), [{MoOCl~3~(Pyz)}~2~O]^2–^ and tetranuclear [(Mo~2~O~4~Cl~4~)~2~(Pyz)~2~]^4–^ anions, with N‐donor ligands engaged either