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Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with Si O 2 N 4 Skeletons Containing Cyanato- N or Thiocyanato- N Ligands †

✍ Scribed by Seiler, Oliver; Burschka, Christian; Fischer, Markus; Penka, Martin; Tacke, Reinhold


Book ID
126003724
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
369 KB
Volume
44
Category
Article
ISSN
0020-1669

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Synthesis and Structural Characterizatio
✍ Stefan Metz; Christian Burschka; Reinhold Tacke 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB 👁 1 views

## Abstract A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)~4~. All the compounds synthesized were structurally characterized by single‐crystal X‐ray diffraction and/or solid‐state NMR spectroscopy. In additio