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Synthesis and Structural Characterization of M(PMe 3 ) 3 (O 2 CR) 2 (OH 2 )H 2 (M = Mo, W): Aqua−Hydride Complexes of Molybdenum and Tungsten

✍ Scribed by Zhu, Guang; Parkin, Gerard


Book ID
127160096
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
67 KB
Volume
44
Category
Article
ISSN
0020-1669

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✍ Li Xu; Zhaohui Li; Huang Liu; Jinshun Huang; Qianer Zhang 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 628 KB

A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120°C to afford