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Synthesis and structural characterization of gallium and indium complexes obtained from redistribution reactions of mixed chalcogen-imidodiphosphinate ligands

✍ Scribed by Mónica Moya-Cabrera; Raymundo Cea-Olivares; Jocelyn Alcántara-García; Rubén A. Toscano; Vojtech Jancik; Verónica García-Montalvo; Simón Hernández-Ortega


Book ID
108188044
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
269 KB
Volume
690
Category
Article
ISSN
0022-328X

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Synthesis and Structural Characterizatio
✍ Reisgys, Martina ;Spies, Hartmut ;Johannesn, Bernd ;Pietzsch, Hans-Jergen ;Leibn 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 493 KB 👁 1 views

Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give