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Synthesis and Structural Characterization of Cobalt, Nickel and Copper Phosphanylthiolato Complexes

✍ Scribed by Patricia Fernández; Antonio Sousa-Pedrares; Jaime Romero; María L. Durán; Antonio Sousa; Paulo Pérez-Lourido; José A. García-Vázquez


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
813 KB
Volume
2010
Category
Article
ISSN
1434-1948

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✍ Krüger, Hans-Jörg 📂 Article 📅 1995 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 1021 KB

The properties of the tetraazamacrocyclic compound N,N 'dimethyl-2,11 -diaza[ 3,3] (2,G)pyridinophane (L-N4Mez) as a ligand for some selected metal chlorides have been examined. The crystal structure of the uncoordinated ligand reveals a syn chair-chair conformation. In solution, the ligand displays