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Synthesis and Structural Characterization of (Carbene)ruthenium Complexes Binding Nucleobases

✍ Scribed by Jean-Luc Fillaut; Isaac de los Rios; Dante Masi; Antonio Romerosa; Fabrizio Zanobini; Maurizio Peruzzini


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
339 KB
Volume
2002
Category
Article
ISSN
1434-1948

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The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual µ 2 ,η 4 :η 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc