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A New Class of Ruthenium Carbene Complexes: Synthesis and Structures of Highly Efficient Catalysts for Olefin Metathesis

✍ Scribed by S. Michael Hansen; Martin A. O. Volland; Frank Rominger; Frank Eisenträger; Peter Hofmann


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
128 KB
Volume
38
Category
Article
ISSN
0044-8249

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A Novel Class of Ruthenium Catalysts for
✍ Thomas Weskamp; Wolfgang C. Schattenmann; Michael Spiegler; Wolfgang A. Herrmann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 1 views

The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities