A Novel Class of Ruthenium Catalysts for
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Thomas Weskamp; Wolfgang C. Schattenmann; Michael Spiegler; Wolfgang A. Herrmann
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Article
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1998
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John Wiley and Sons
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English
⚖ 128 KB
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The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities