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Synthesis and structural characterization of an unusual η3-ligated 1,3-diphosphacyclobutadiene molybdenum complex via cyclodimerization of a phosphaalkyne. Crystal structure of [Mo(η5-C9 H7)(CO)2P-η3-(tBu)CPC(tBu)PFBF3]

✍ Scribed by Peter B. Hitchcock; Mohd Jamil Maah; John F. Nixon; Michael Green


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
523 KB
Volume
466
Category
Article
ISSN
0022-328X

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Synthesis and Structure of the First η3-
✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C