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Synthesis and structural characterization of alkaline–earth complexes containing a triazole-based selenide ligand

✍ Scribed by Balanta-Díaz, Jhon A.; Moya-Cabrera, Mónica; Jancik, Vojtech; Jesús Morales-Juárez, T.; Cea-Olivares, Raymundo

Book ID
121210162
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
992 KB
Volume
63
Category
Article
ISSN
0277-5387

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The chemical behavior of triazole, thiadiazole, and triazoline derivatives of thiocarbonohydrazide towards cis-[RuCl 2 (DMSO) 4 ] (2) was studied. Reaction of 4-amino-5methylthio-3-(2-pyridyl)-1,2,4-triazole (L1) with 2 gave two diastereomeric complexes, trans,cis-[RuCl 2 (DMSO) 2 (L1)] (3) and chir