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Rare earth metal complexes bearing thiophene-amido ligand: Synthesis and structural characterization

✍ Scribed by Wang, Dun; Cui, Dongmei; Miao, Wei; Li, Shihui; Huang, Baotong


Book ID
121411408
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
173 KB
Volume
40
Category
Article
ISSN
1477-9226

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The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual µ 2 ,η 4 :η 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc