Synthesis and structural characterisation of a pair of linkage isomers of copper(I0 pyridine-2-carbaldehyde 2′-pyridylhydrazone complexes
✍ Scribed by Eric W. Ainscough; Andrew M. Brodie; Scott L. Ingham; Joyce M. waters
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 984 KB
- Volume
- 249
- Category
- Article
- ISSN
- 0020-1693
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A novel 1D coordination polymer, [Cu(picOH) 2 (BPE)] (IIa), and neutral [Cu(picOH) 2 (BPE) 2 ] (IIb) complexes, can be simultaneously isolated (structure II) when neutral [Cu(picOH) 2 ] (I) species are axially bridged by 1,2-bis(4-pyridyl)ethane (BPE) molecules. The compound has been characterised s