Synthesis and Structural Analysis of Dehydrophenylalanine Cyclophanes.
β Scribed by Susan E. Gibson; Jerome O. Jones; S. Barret Kalindjian; Jamie D. Knight; Jonathan W. Steed; Matthew J. Tozer
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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The acceptor-porphyrin cyclophanes 2 and 4 with acceptor-porphyrin cyclophanes are discussed based on 1 H-NMR and the X-ray structural analysis of 2. According to the pyromellitic diimide (1) as strong electron-acceptor, and the corresponding porphyrin zinc complexes 3 and 5 were results obtained, t
Small hydrocarbon cyclophanes, such as [2.2.0]m,m,m-cyclophane ( ) and [2.2.0]p,m,m-cyclophane (21), are strained analogues of the well-known Ο-prismand [2.2.2]p,p,p-cyclophane (1). The synthetic route to these molecules is based on well-established cyclophane methodology which offers a general acce