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Small Hydrocarbon Cyclophanes: Synthesis, X-ray Analysis and Molecular Modelling

โœ Scribed by Tanja Lahtinen; Elina Wegelius; Juha Linnanto; Kari Rissanen

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
176 KB
Volume
2002
Category
Article
ISSN
1434-193X

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โœฆ Synopsis

Small hydrocarbon cyclophanes, such as [2.2.0]m,m,m-cyclophane ( ) and [2.2.0]p,m,m-cyclophane (21), are strained analogues of the well-known ฯ€-prismand [2.2.2]p,p,p-cyclophane (1). The synthetic route to these molecules is based on well-established cyclophane methodology which offers a general access to a whole family of hydrocarbon cyclophanes. Single crystal X-ray analysis and molecular model-

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