๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Synthesis and stereoselective aldol reaction of dihydroxyacetone derivatives

โœ Scribed by Kwan Soo Kim; Sung Don Hong

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
155 KB
Volume
41
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

Ecient synthetic methods for 1,3-di-O-benzyldihydroxyacetone (3) and 1,3-O-cyclohexylidenedihydroxyacetone (8) were developed. TiCl 4 -mediated aldol reaction of the silyl enol ether of 3 with aldehydes gave syn aldol products while the reaction of the silyl enol ether of 8 with aldehydes aorded anti aldol products.

๐Ÿ“œ SIMILAR VOLUMES

Synthesis of acyl dihydroxyacetone phosp
Synthesis of acyl dihydroxyacetone phosphates and related derivatives
โœ Claude Piantadosi; Kun Chae; Khalid S. Ishaq; Fred Snyder ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 416 KB

The chemical syntheses of I-0-palmitoyl-and 1-0acetyl-2,2-dirnethoxypropane-3-phosphate cyclohexylammonium salt and I-O-palmitoyl-2,2-dimethoxypropane-3-O-phosph,orylethanolamine are reported. The acyl dihydroxyacetone phosphates can serve as intermediates in the pathway for the biosynthesis of phos